Automated preparation of biological samples prior to high pressure liquid chromatography: Part I- The use of dialysis deproteinizing serum for amino-acid analysis
1985

Automated Preparation of Biological Samples for Amino-Acid Analysis

publication Evidence: moderate

Author Information

Author(s): D. C. Turnell, J. D. H. Cooper

Primary Institution: Department of Biochemistry, Coventry and Warwickshire Hospital

Hypothesis

Can dialysis be effectively used for the deproteinization of serum samples in automated amino-acid analysis?

Conclusion

The study demonstrates that combining dialysis with an automated derivatization system can effectively prepare serum samples for amino-acid analysis.

Supporting Evidence

  • The automated system can perform sampling, dialysis, derivatization, and injection onto the HPLC in only 135 seconds.
  • The mean analytical recovery of amino acids was found to be 101% with a standard deviation of 2.3%.
  • Using a double lumen probe maximizes the load volume to dead volume ratio in the system.

Takeaway

This study shows a way to automate the process of preparing blood samples to check for amino acids, making it easier and faster.

Methodology

The study utilized an automated system combining dialysis and pre-column derivatization for amino-acid analysis via HPLC.

Limitations

The method may not achieve maximum recovery of amino acids due to the 60-second dialysis time used.

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